Selective ring opening of silylated vinyloxiranes and reactivity of azido-alcohols
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چکیده
منابع مشابه
synthesis of sulfides from alcohols and thiols in solvent-freeconditions and deoxygenation of sulfoxides
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متن کاملSynthesis and reactivity of silylated tetrathiafulvalenes.
Novel organosilylated tetrathiafulvalenes (TTFs) possessing Si-H or Si-Si bonds have been synthesised. The crystal structures of several derivatives have been determined by X-ray diffraction, including that of dimeric (Si2Me4)(TTF)2 (11) incorporating a diatomic SiMe2-SiMe2 linker. Cyclic voltammetry measurements in all cases show two oxidation waves. DFT calculations were performed to rational...
متن کاملMagnesium Oxide Nanoparticles for Catalytic Synthesis of 2-Substituted Alcohols from Regioselective Ring Opening of Epoxides in Water
Epoxides undergo regioselective ring opening with various nucleophiles using catalytic amount of nano magnesium oxide and water as solvent under mild reaction conditions. The remarkable features of this method are improved yields, high regioselectivity, and green chemistry agreement.
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ژورنال
عنوان ژورنال: Arkivoc
سال: 2007
ISSN: 1551-7012
DOI: 10.3998/ark.5550190.0008.521